Rydberg Spectral Properties of Endohedrally Confined H Atoms Obtained by B-spline Basis Set
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Graphical Abstract
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Abstract
Rydberg energy levels and oscillator strength of endohedrally confined H atom have been calculated by using a nonlinear algebraic mapping technique and B-spline method.The boundary conditions are conveniently satisfied with a specially designing knot sequence.Our results show that endohedral can selectively alter the properties and energy levels of Rydberg atoms, and such atoms possess some properties and behaviours which are not previously met or studied in free systems.
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